A total of 71 specimens of Antillean scorpions belonging to three families [Liochelidae, Scorpionidae (Diplocentrinae), and Buthidae] and seven genera are deposited at the Montana Entomology Collection (MTEC) of the Montana State University. The most represented genus is Tityus C. L. Koch, 1836, which contains seven species from Dominican Republic. Those materials are from the following countries: Cuba, Dominican Republic, U.S. Virgin Islands, British Virgin Islands, Montserrat, and St. Kitts. The male of Tityus septentrionalis Armas & Abud Antun, 2004 is described for the first time.